The large-scale adoption of wind and solar power calls for technologies that store electrical energy at low cost. Among the major approaches for storing electrical energy (batteries, solar fuels, solar thermal), only batteries have emerged as practical, commercially viable devices. Thus, batteries are on track to bring about a revolution in transportation: within 15 years, most major vehicle manufacturers (Ford, GM, Volvo, VW) will entirely phase out gas- and diesel-powered vehicles.
The rapid expansion in lithium-ion batteries poses challenges, however, and many research groups are exploring alternatives to lithium. Although other cations (Na, Mg, Ca, Zn) have attracted widespread interest, our group has taken a divergent strategy: the development of batteries that shuttle anions such as fluoride.
Until recently, there were no viable liquid electrolytes for a fluoride-ion battery. This changed in 2018, however, with the development of the first fluoride-conductive liquid electrolyte. The availability of this electrolyte is now permitting the first room-temperature studies of electrodes for the fluoride-ion battery.
Many of our computational and experimental studies seek to discover new electrodes for the fluoride-ion battery. For example, we recently reported that Y2C and Sc2C can store two fluoride ions per formula unit, providing storage capacities well above commercial lithium-ion batteries (patents pending). The possibility of achieving high-performance, low-cost electrical energy storage using earth-abundant elements continues to motivate our research efforts to address sustainability.
The development of new batteries—and of technologies in general—requires new materials. The central aim of our lab is the discovery of new inorganic materials for energy applications.
The periodic table has over 100 elements. There are more than 1002 ways to combine two elements (“binaries”) and over 1003 ways to combine three elements (“ternaries”). Even among binary compounds, most remain undiscovered. Discovering, understanding, and using these compounds will be a cornerstone of addressing important societal challenges.
Our efforts in discovery are currently focused on two types of materials: electrides and 2D materials.
Electrides are an exotic class of ionic solids. Unlike conventional ionic solids, the site that would normally hold an anion instead holds a bare electron. For example, one can imagine replacing all the Cl- in NaCl with an electron. Although this hypothetical material does not actually exist (Na+ and a bare electron would spontaneously recombine to form sodium metal), there are materials in which the bare electron is stable. One such material is Sc2C—a material our lab discovered—which can be written as [Sc2C]2+·2e-. In this material, the atoms maintain a net positive charge and are balanced by sites that hold negatively charged electrons.
The chemical and physical properties of bare electrons are fundamentally different from conventional anions, and these differences often lead to properties that are more extreme—often more useful—than conventional materials. For example, in the electride [Ca2N]2+·2e-, the electride electrons give rise to electrical conductivity that rivals silver and the electrons are better electron donors than most alkali metals. These exceptional properties motivate our further exploration of this exciting class of materials.
(2) 2D materials
Most of the electrides that we study have layered structures, and this naturally led us to explore 2D materials as well. Our lab is generally interested in synthesizing and exploring new types of 2D materials, and our discovery of several new 2D materials are among our more important contributions.
Beginning in 2013, we developed a new method to exfoliate black phosphorus to form phosphorene. Phosphorene is exciting because it becomes quantum confined as a 2D material, exhibiting a highly tunable band gap. Now, our approach for synthesizing phosphorene is used to make a commercial product.
Our lab has several active projects that are explore the synthesis and structure-property relationships in other new classes of 2D materials.